Hydrosulfide complexes of the transition elements: diverse roles in bioinorganic, cluster, coordination, and organometallic chemistry
Michael D. Pluth, Zachary J. Tonzetich
Abstract
to d-block elements produces a unique class of substances that differ in significant ways from more ubiquitous metal thiolates. This review examines the preparation, structure, spectroscopy, and reactivity of such compounds and the roles they play across several fields of chemistry.
Topics & Concepts
Bioinorganic chemistryChemistryCoordination complexOrganometallic chemistryCluster (spacecraft)Group 2 organometallic chemistryTransition metalStereochemistryOrganic chemistryMoleculeMetalCatalysisComputer scienceProgramming languageMetalloenzymes and iron-sulfur proteinsSulfur Compounds in BiologyOrganometallic Compounds Synthesis and Characterization