Experimental investigations into the irregular synthesis of iron(<scp>iii</scp>) terephthalate metal–organic frameworks MOF-235 and MIL-101
Isabelle Simonsson, Philip Gärdhagen, Moira Andrén, Pui Lam Tam, Zareen Abbas
Abstract
) in a large yield and at a previously unreported temperature (80 °C vs. previously used 110-150 °C). In situ X-ray scattering was utilized to investigate the crystallization of MOF-235 and MIL-101. At 80 °C, only MOF-235 formed and at 85 and 90 °C, only MIL-101 formed.
Topics & Concepts
Metal-organic frameworkMaterials scienceMetalChemical engineeringNanotechnologyChemistryOrganic chemistryMetallurgyEngineeringAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsZeolite Catalysis and SynthesisMagnetism in coordination complexes