Thermodynamics of the self-assembly of <i>N</i>-annulated perylene bisimides in water. Disentangling the enthalpic and entropic contributions
Manuel A. Martínez, Daniel Aranda, Enrique Ortı́, Juan Aragó, Luis Sánchez
Abstract
The hydrophilic/hydrophobic ratio and the number of water molecules released during the self-assembly of N -PBIs 1–4 condition the enthalpic and entropic contributions associated with the self-assembly of these dyes.
Topics & Concepts
PeryleneChemistryMoleculeSelf-assemblyHydrophobic effectThermodynamicsChemical physicsComputational chemistryOrganic chemistryPhysicsSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence ChemistryLuminescence and Fluorescent Materials