Coordination chemistry of mercury(<scp>ii</scp>) halide complexes: a combined experimental, theoretical and (ICSD & CSD) database study on the relationship between inorganic and organic units
Ali Samie, Alireza Salimi, Jered C. Garrison
Abstract
, naphthalene-6-yl pyrazine-2-carboxylate (complexes 10-11) were synthesized and fully characterized. The various parameters of substitution, C-H to nitrogen replacement, counteranion, and symmetry effects were investigated for all of the complexes. The results show that there is a meaningful relationship between inorganic and organic units. According to the findings of the CSD and ICSD analyses, most of the complexes obeyed the same relationship. Despite the predominant role of the inorganic unit in determining the coordination geometry, the organic unit can also change the coordination sphere of complexes with one major effect or the cooperativity of minor effects.
Topics & Concepts
Mercury (programming language)HalideChemistryDatabaseEnvironmental chemistryInorganic chemistryComputer scienceProgramming languageCrystallography and molecular interactionsChemical Thermodynamics and Molecular StructureRadioactive element chemistry and processing