A Comprehensive Review of the Influence of Sensitizers on the Detonation Properties of Emulsion Explosives
A. Maranda, Dorota Siuta, Bożena Kukfisz, Weronika Jakubczak
Abstract
Emulsion explosives are extensively utilized in the global mining industry due to their superior water resistance, high safety standards, cost-efficiency, and robust performance. The basic component of these explosives is a water-in-oil emulsion matrix, which, in its initial state, lacks the capacity for detonation. The sensitization process, achieved through either physical or chemical means, is a critical step that enhances the emulsion’s sensitivity to detonation, thereby improving its operational efficiency in blasting applications. This review presents a comprehensive and systematic analysis of the current scientific literature and experimental investigations concerning the impact of key sensitizing methods and agents on the detonation characteristics of emulsion explosives. Particular emphasis is placed on the classification of sensitizers, their physicochemical properties, and their interactions with the emulsion matrix. By examining various sensitization mechanisms, this study provides insights into the role and efficacy of both established and emerging sensitizing agents. The findings of this review highlight the pivotal role of sensitizer selection in defining the detonation performance of emulsion explosives, with implications for enhancing safety standards and ensuring the protection of both industrial operations and public safety. The most optimal sensitization method is chemical, utilizing cost-effective components that generate gas bubbles within the matrix. A key advantage is the in situ production of emulsion explosives, which eliminates the need for their transport on public roads, thereby enhancing safety and reducing the risk of terrorist threats.