Acyloxy, sulfate, and phosphate radicals as hydrogen atom transfer (HAT) agents for direct C(sp<sup>3</sup>)–H functionalization
Jia‐Lin Tu, Binbin Huang
Abstract
This tutorial review focuses on the recent advancements in HAT-based direct C(sp 3 )–H bond functionalization with three unique classes of oxygen radicals: acyloxy, sulfate, and phosphate radicals.
Topics & Concepts
Surface modificationRadicalChemistryHydrogen atomPhosphateSulfatePhotochemistryCombinatorial chemistryOrganic chemistryGroup (periodic table)Physical chemistrySynthesis and Catalytic ReactionsRadical Photochemical ReactionsOxidative Organic Chemistry Reactions