A novel multichromic Zn(<scp>ii</scp>) cationic coordination polymer based on a new flexible viologen ligand exhibiting aniline detection in the solid state
Jia yun Zou, Jie Ji, Mei hong Fan, Jia yu Li, Hai Yu Wang, Guodong Li
Abstract
In this work, a novel multichromic cationic coordination polymer, named [Zn4(BTC)3(bcbpy)2]·5H2O (1), based on a new flexible viologen ligand 1,1'-bis(3-cyanobenzyl)-[4,4'-bipyridine]-1,1'-diium (H2bcbpy·2Cl), Zn(NO3)2·6H2O and pyromellitic acid (H4BTC) was synthesized. Compound 1 has good photosensitive activity and can respond to sunlight at room temperature. The colour of compound 1 changes rapidly in response to UV light and blue ray irradiation within 5 s. We rarely obtained the crystal structures after irradiation under UV light and blue ray. At the same time, compound 1 shows the hydrochromism phenomenon when heated at 120 °C, and it also shows the ability of detecting aniline and NO2- under low-concentration conditions (10-4 M).