Electrochemical conversion of CO<sub>2</sub> in non‐conventional electrolytes: Recent achievements and future challenges
Elizabeth Sargeant, Paramaconi Rodríguez
Abstract
Abstract Electrochemical reduction of CO 2 in traditional aqueous electrolytes suffers from low faradaic efficiency towards desired products which can be traced back to low CO 2 solubility and strong competition from the hydrogen evolution reaction. The use of non‐conventional electrolytes aims to mitigate these issues. This review will give a focused overview summarizing some of the most recent contributions on the electrochemical conversion of CO 2 in organic solvents, ionic liquids, solid electrolytes, and brines. We summarize the findings in terms of activity, selectivity, and durability for each of the systems. In addition, it provides an outlook about the role of water, cations, and anions in the reaction. We also highlight the challenges of the electrochemical reduction of CO 2 in each of the electrolytes. All the studies referred to in this review contribute meaningfully to reaching the technical targets for CO 2 electrolyzers in non‐conventional electrolytes.