Suppression of cavitation-induced nucleation in systems under isochoric confinement
Anthony N. Consiglio, Gideon Ukpai, Boris Rubinsky, Matthew J. Powell‐Palm
Abstract
This work explores the effects of constant volume confinement on cavitation-induced ice nucleation by marrying fluid dynamics, thermodynamics, and nucleation kinetics into a single approach. The authors find that confinement at even macroscopic volumes can suppress cavitation-induced nucleation from single microscale bubbles, suggesting that macroscale confinement may provide an effective method of suppressing this nucleation pathway in supercooled aqueous systems.
Topics & Concepts
NucleationIsochoric processCavitationMicroscale chemistrySupercoolingMaterials scienceWork (physics)ThermodynamicsChemical physicsChemistryPhysicsMathematics educationMathematicsnanoparticles nucleation surface interactionsCalcium Carbonate Crystallization and InhibitionArctic and Antarctic ice dynamics