A hydrofluoric acid-free synthesis of 2D vanadium carbide (V <sub>2</sub> C) MXene for supercapacitor electrodes
Yunfeng Guan, Song Jiang, Ye Cong, Jiapei Wang, Zhijun Dong, Qin Zhang, Guanming Yuan, Yanjun Li, Xuanke Li
Abstract
Abstract Although theoretical calculations predict vanadium carbide (V 2 C) MXene may possess superior performances as electrodes of supercapacitors and lithium-ion batteries, a milder synthesis process of high-purity V 2 C MXene undoubtedly becomes one of the greatest hindrances for extending its applications. Herein, we report a hydrofluoric acid (HF)-free synthesis of 2D V 2 C MXene by milder etching V 2 AlC powders in the mixture of lithium fluoride and hydrochloric acid. The etching time plays vital roles on the structure and morphology of V 2 C MXene. The as-synthesized V 2 C MXene etched for 120 h displays a uniform multilayered structure and higher purity (>90%). All that matter is it exhibits a maximum specific capacitance of 164 F g −1 at a scan rate of 2 mV s −1 , good cycling stability and high specific capacitance retention (~90% after 10 000 cycles at 5 A g −1 ) in 1 M Na 2 SO 4 electrolyte. Moreover, other fluorides, including potassium fluoride, sodium fluoride and ammonium hydrogen fluoride, are also testified to be effective to obtain highly pure V 2 C MXene. This work provides the certainty for synthesizing MXenes besides Ti 3 C 2 via a HF-free etching process to beneficially expand their promising application.