Beyond the Scholl reaction – one-step planarization and edge chlorination of nanographenes by mechanochemistry
Daniel M. Baier, Sven Grätz, Babak Farhadi Jahromi, Sarah Hellmann, Konrad Bergheim, Wilm Pickhardt, Rochus Schmid, Lars Borchardt
Abstract
-hexabenzocoronene is conducted mechanochemically. This approach overcomes solubility limitations and eliminates the need for elaborate chlorination conditions. Additionally, the planarization of oligophenylenes and their edge-chlorination can be combined in a one-pot approach requiring as little as 60 minutes.
Topics & Concepts
Chemical-mechanical planarizationMechanochemistryTriphenyleneEnhanced Data Rates for GSM EvolutionSolubilityMaterials scienceChemistryChemical engineeringNanotechnologyOrganic chemistryComputer scienceEngineeringLayer (electronics)MoleculeTelecommunicationsPorphyrin and Phthalocyanine ChemistryGraphene research and applicationsLuminescence and Fluorescent Materials