When SF<sub>5</sub> outplays CF<sub>3</sub>: effects of pentafluorosulfanyl decorated scorpionates on copper
Anurag Noonikara‐Poyil, Alvaro Muñoz‐Castro, Andrii Boretskyi, Pavel K. Mykhailiuk, H. V. Rasika Dias
Abstract
Copper–ethylene and carbonyl complexes of the newly developed [Ph 2 B(3-(SF 5 )Pz) 2 ] − enable the study of ligand steric and electronic effects caused by the –SF 5 group (dubbed “super CF 3 ”), and a comparison to the –CF 3 bearing analogs.
Topics & Concepts
Steric effectsCopperChemistryLigand (biochemistry)Electronic effectEthyleneGroup (periodic table)StereochemistryOrganic chemistryBiochemistryCatalysisReceptorFluorine in Organic ChemistryInorganic Fluorides and Related CompoundsOrganoboron and organosilicon chemistry