Binary-Encounter Model for Direct Ionization of Molecules by Positron-Impact

Abstract

We introduce two models for the computation of direct ionization cross sections by positron impact over a wide range of collision energies. The models are based on the binary-encounter-Bethe model and take into account an extension of the Wannier theory. The cross sections computed with these models show good agreement with experimental data. The extensions improve the agreement between theory and experiment for collision energies between the first ionization threshold and the peak of the cross section. The models are based on a small set of parameters, which can be computed with standard quantum chemistry program packages.

Topics & Concepts