In Situ Conversion of Ti<sub>3</sub>C<sub>2</sub> MXene to Sandwich Ti<sub>3</sub>C<sub>2</sub>/R-TiO<sub>2</sub> for Promoted Photocatalytic Hydrogen Production
Ke Wei, Jiuxiang Yang, Fang-Yuan Bai, Yuan-Sheng Shen, Kai Liu, Jing Liu, Lihua Chen, Yu Li, Bao‐Lian Su
Abstract
Ti 3 C 2 MXene has been extensively studied in the field of photocatalytic hydrogen production since its discovery due to the large specific surface area and adjustable surface groups. However, the weak interaction at the interface of Ti 3 C 2 -based composites leads to a high energy barrier, which is not conducive to carrier transport. Herein, we propose the construction of a sandwich Ti 3 C 2 /R-TiO 2 composite photocatalyst by in situ growing rutile TiO 2 (R-TiO 2 ) nanoneedles in Ti 3 C 2 MXene through NaOH oxidation treatment and the microwave hydrothermal method. This in situ synthesis can make Ti 3 C 2 MXene and TiO 2 nanoneedles closely link together, which is conducive to carrier transport and material stability. The best Ti 3 C 2 /R-TiO 2 composite achieves an excellent hydrogen production rate of 1.62 mmol g –1 h –1, as endowed by the 2D nanosheet-constructed sandwich structure, an increased specific surface area, and improved charge carrier separation and transport.