The effects of morphology and temperature on the tensile characteristics of carbon nitride nanothreads
Yuequn Fu, Ke Xu, Jianyang Wu, Zhiliang Zhang, Jianying He
Abstract
-cage shows extreme ductility because of the formation of a linear polymer via 4-step dissociation-and-reformation of bonds at extremely low temperatures in the range of 1-15 K; however, it shows brittle failure at one cross-section with low ductility at higher temperatures similar to other CNNTs at different temperatures; this offers a feasible way to design a kind of lightweight material that can be used in ultra-low temperature conditions, for example, the harsh deep space environment. The results also show that temperature significantly affects the fracture stress and rupture strain but not the effective stiffness. The analysis of atomic bond orders and bond lengthening reveals that the unique nonlinear elasticity of CNNTs is attributed to the occurrence of local bond transformations. This study provides physical insights into the tensile characteristics of CNNTs for the design and application of CNNT-based nanostructures as multifunctional materials.