Cooperative photoredox and N-heterocyclic carbene-catalyzed formal C–H acylation of cyclopropanes <i>via</i> a deconstruction–reconstruction strategy
Fan Gao, Tian Wang, Xiaoyu Yan
Abstract
Cooperative NHC/photoredox catalyzed deconstruction–reconstruction of aryl cyclopropanes was described to access various α-acylated cyclopropane derivatives.
Topics & Concepts
CarbeneAcylationDeconstruction (building)CatalysisChemistryCombinatorial chemistryOrganic chemistryBiologyEcologyCyclopropane Reaction MechanismsCatalytic C–H Functionalization MethodsN-Heterocyclic Carbenes in Organic and Inorganic Chemistry