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Oxidation of Organic Compounds Using Water as the Oxidant with H<sub>2</sub> Liberation Catalyzed by Molecular Metal Complexes

Sayan Kar, David Milstein

2022Accounts of Chemical Research55 citationsDOIOpen Access PDF

Abstract

liberation. The oxidation of alcohols, aldehydes, amines, alkenes, and enol ethers will be discussed to provide an outlook toward other functional groups' oxidation. We hope that this will aid researchers in devising other oxidative dehydrogenative catalytic systems using water, complementing traditional oxidative processes involving strong oxidants and molecular oxygen.

Topics & Concepts

ChemistryCatalysisHydrogen peroxideRutheniumAqueous solutionRhodiumCarboxylateChlorineOrganic chemistryOxygenInorganic chemistryOxidative Organic Chemistry ReactionsAsymmetric Hydrogenation and CatalysisChemical Synthesis and Reactions
Oxidation of Organic Compounds Using Water as the Oxidant with H<sub>2</sub> Liberation Catalyzed by Molecular Metal Complexes | Litcius