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Recent Advances on High-Order Dipolar Annulations of Donor–Acceptor Cyclopropanes/Cyclobutanes

Shiyong Peng, Liangliang Yang, Haiyang Wang, Ming Lang

2023Synthesis23 citationsDOI

Abstract

Abstract This short review summarizes the recent impressive developments on the high-order dipolar annulations (HODAs) of donor–acceptor cyclopropanes (DACs) and donor–acceptor cyclobutanes (DABs) to afford medium-sized (hetero)cycles. 1 Introduction 2 (3+m) (m > 3) Annulations of Donor–Acceptor Cyclopropanes 2.1 (3+4) Annulations 2.2 (3+5) Annulations 3 (4+m) (m > 2) Annulations of Donor–Acceptor Cyclobutanes 4 Conclusion

Topics & Concepts

CyclobutanesChemistryAcceptorCatalysisOrganic chemistryCycloadditionPhysicsCondensed matter physicsCyclopropane Reaction MechanismsAsymmetric Synthesis and CatalysisCatalytic Alkyne Reactions
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