Evidence for stereoelectronic effects in ligand exchange reactions on Au<sub>25</sub> nanoclusters
Yanan Wang, Thomas Bürgi
Abstract
cluster. It is demonstrated that the fluorine-substituted BINAS significantly decreases the LER reactivity both at the molecule and the related cluster level. The stereoelectronic effect is global and can be transmitted to the cluster surface. In contrast, the stereospecific effect is marginal.
Topics & Concepts
NanoclustersLigand (biochemistry)Cluster (spacecraft)ChemistryComputational chemistryStereochemistryOrganic chemistryComputer scienceProgramming languageReceptorBiochemistryNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis