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Hydrogen evolution reaction mechanism on Ti<sub>3</sub>C<sub>2</sub> MXene revealed by <i>in situ</i>/operando Raman spectroelectrochemistry

Denis Johnson, Hao-En Lai, Kyle Hansen, Perla B. Balbuena, Abdoulaye Djire

2022Nanoscale45 citationsDOIOpen Access PDF

Abstract

formation. This results in an overcharging of the structure that leads to the observed large HER overpotential. This study provides new insights into the HER mechanisms of MXene catalysts and a pathway forward to design efficient and cost-effective catalysts for HER and related electrochemical energy conversion systems.

Topics & Concepts

Raman spectroscopyIn situMaterials scienceReaction mechanismMechanism (biology)HydrogenNanotechnologyPhotochemistryChemistryCatalysisPhysicsOpticsOrganic chemistryQuantum mechanicsMXene and MAX Phase Materials2D Materials and ApplicationsAdvanced Photocatalysis Techniques