Gold-catalyzed alkenylation and arylation of phosphorothioates
Urvashi Urvashi, Sampoorna Mishra, Nitin T. Patil
Abstract
generated Ag-sulfur complex, which undergoes a facile transmetalation with the Au(iii) intermediate, thereby leading to the successful realization of the present reaction. Moreover, for the first time, the alkenylation of phosphoroselenoates under gold redox catalysis has been presented.
Topics & Concepts
TransmetalationCatalysisChemistryLigand (biochemistry)Combinatorial chemistryArylRedoxSulfurOrganic chemistryBiochemistryReceptorAlkylSulfur-Based Synthesis TechniquesCatalytic Alkyne Reactions