Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin
Teresa Kösel, Göran Schulz, Gerald Dräger, Andreas Kirschning
Abstract
This report discloses the photochemical homolytic cleavage of iodine azide after its formation following release from polymer-bound bisazido iodate(I) anions. A series of radical reactions are reported including the 1,2-functionlization of alkenes and the unprecedented chemoselective oxidation of secondary alcohols in the presence of primary alcohols.
Topics & Concepts
ChemistryAzideIodateIodinePhotochemistryHomolysisIon-exchange resinBond cleavageRadicalOrganic chemistryCatalysisOxidative Organic Chemistry ReactionsSynthesis and Biological EvaluationRadical Photochemical Reactions