Supramolecular-controlled regioselective photochemical [4 + 4] cycloaddition within Cp*Rh-based metallarectangles
Sha Bai, Lifeng Wang, Zhenwei Wu, Ting Feng, Ying‐Feng Han
Abstract
photo- and thermal cleavage reactions, even after repeating three times. Furthermore, pure organic photodimers 3a and 3b, which are difficult to synthesize by conventional organic methods, can be readily dissociated from the metalloassemblies in high yields.
Topics & Concepts
CycloadditionRegioselectivityAnthraceneChemistryRhodiumSupramolecular chemistryPhotochemistryReactivity (psychology)MoleculeCombinatorial chemistryOrganic chemistryCatalysisAlternative medicinePathologyMedicinePhotochromic and Fluorescence ChemistrySynthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in Materials