Heterogeneous catalysis with an organic–inorganic hybrid based on MoO<sub>3</sub> chains decorated with 2,2′-biimidazole ligands
Tatiana R. Amarante, Patrícia Neves, Filipe A. Almeida Paz, Ana C. Gomes, Martyn Pillinger, Anabela A. Valente, Isabel S. Gonçalves
Abstract
Polymeric [MoO<sub>3</sub>(2,2′-biimidazole)]·H<sub>2</sub>O outperforms other one-dimensional MoO<sub>3</sub>-ligand hybrid materials as a heterogeneous and recyclable catalyst for (bio)olefin epoxidation and sulfoxidation.
Topics & Concepts
CatalysisOlefin fiberLigand (biochemistry)ChemistryHeterogeneous catalysisPolyoxometalateHybrid materialCombinatorial chemistryOrganic chemistryMaterials scienceReceptorBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions