Light-induced aryldifluoromethyl-sulfonylation/thioetherification of alkenes using arenethiolates as a photoreductant and sulfur source
Jiayu Li, Zipeng Guo, Xiaofeng Zhang, Xiao‐Li Meng, Zhenyang Dai, Meiyun Gao, Shuo Guo, Pingping Tang
Abstract
A novel ATRA reaction was developed from simple and widely accessible alkenes, thiols, and trifluoromethylarenes vis photo-induced EDA complex strategy. Several complicated bioactive molecules undergo smoothly the one-pot photosynthetic process.
Topics & Concepts
SulfurChemistryCombinatorial chemistryMoleculeOrganic chemistryPhotochemistrySulfur-Based Synthesis TechniquesFluorine in Organic ChemistryRadical Photochemical Reactions