Local electric field in nanocavities dictates the vibrational relaxation dynamics of interfacial molecules
Xiaoxuan Zheng, Quanbing Pei, Junjun Tan, Shiyu Bai, Yi Luo, Shuji Ye
Abstract
are strongly correlated with the reported macroscopic chemical reactivity. This finding may aid in enriching the current understanding of PMCRs and highlights the possibility of regulating vibrational energy flow into desired reaction coordinates by using a local electric field.
Topics & Concepts
Electric fieldVibrational energy relaxationRelaxation (psychology)MoleculeUltrashort pulseDynamics (music)Chemical physicsField (mathematics)Molecular dynamicsVibrational energyMolecular vibrationSpectroscopyMolecular physicsMaterials scienceAtomic physicsChemistryPhysicsComputational chemistryOpticsLaserQuantum mechanicsAcousticsMathematicsPsychologyPure mathematicsSocial psychologySpectroscopy and Quantum Chemical StudiesPhotochemistry and Electron Transfer StudiesPhotoreceptor and optogenetics research