Self-assembly of conformation-adaptive dihydrophenazine-based coordination cages
Meng‐Xiang Wu, Qiong‐Yan Hong, Minghui Li, Wei‐Ling Jiang, Bin Huang, Shuai Lu, Heng Wang, Hai‐Bo Yang, Xiao‐Li Zhao, Xueliang Shi
Abstract
-type one, mainly driven by the anion template effect. All coordination cages were confirmed through single-crystal X-ray diffraction, and their structural conformations underwent great changes compared with those of their corresponding ligands. Moreover, the conformational changes also significantly affected their photophysical and electrochemical properties which were distinct from their parent ligands.
Topics & Concepts
ChemistryCrystallographyNanotechnologyMaterials scienceSupramolecular Chemistry and ComplexesMagnetism in coordination complexesLanthanide and Transition Metal Complexes