Catalytic asymmetric inverse-electron-demand aza-Diels–Alder reaction of 1,3-diazadienes with 3-vinylindoles
Yu‐Hang Miao, Yuan‐Zhao Hua, Hao‐Jie Gao, Nan-Nan Mo, Min‐Can Wang, Guang‐Jian Mei
Abstract
A facile chiral phosphoric-acid catalyzed asymmetric inverse-electron-demand aza-Diels–Alder reaction of 1,3-diazadienes with 3-vinylindoles was established.
Topics & Concepts
StereocenterPhosphoric acidCatalysisChemistryYield (engineering)InverseDiels–Alder reactionDual (grammatical number)Combinatorial chemistryMedicinal chemistryOrganic chemistryEnantioselective synthesisMaterials scienceMathematicsGeometryMetallurgyArtLiteratureAsymmetric Synthesis and CatalysisSynthesis and Catalytic ReactionsOxidative Organic Chemistry Reactions