Intramolecular hydrogen bond-induced high chemical stability of metal–organic frameworks
Keke Wang, Qunmin Wang, Xiong Wang, Mei Wang, Qin Wang, Hai‐Min Shen, Yun‐Fang Yang, Yuanbin She
Abstract
Intramolecular hydrogen bonds in ligands restrict the rotation of carboxyl groups and consequently enhance the chemical stability of MOFs.
Topics & Concepts
Intramolecular forceHydrogen bondChemical bondChemical stabilityChemistryMetalHydrogenMaterials sciencePhotochemistryMoleculeOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesCrystallography and molecular interactions