Construction of diverse polycyclic N-heterocycles <i>via</i> cascade allylic amination/Diels–Alder reaction
Zhenkun Yang, Hongling Xie, Luning Tang, Jianwei Sun, Zhengyu Han, Hai Huang
Abstract
An efficient cascade approach for the construction of nitrogen-containing polycyclic compounds from amines tethered with an alkenyl (or alkynyl) group and divinyl carbonates is described.
Topics & Concepts
Allylic rearrangementAminationDiels–Alder reactionChemistryCascadeOrganic chemistryCombinatorial chemistryCatalysisChromatographyAsymmetric Hydrogenation and CatalysisCatalytic C–H Functionalization MethodsSynthetic Organic Chemistry Methods