Litcius/Paper detail

Membrane electrode assembly design to prevent CO2 crossover in CO2 reduction reaction electrolysis

Hung-Ming Joseph Chang, Iryna V. Zenyuk

2023Communications Chemistry21 citationsDOIOpen Access PDF

Abstract

To reach a net-zero energy economy by 2050, it is critical to develop negative emission technologies, such as CO2 reduction electrolyzers, but these devices still suffer from various issues including low utilization of CO2 because of its cross-over from the cathode to the anode. This comment highlights the recent innovative design of membrane electrode assembly, utilizing a bipolar membrane and catholyte layer that blocks CO2 cross-over and enables high CO2 single-pass utilization. To reach a net-zero energy economy by 2050, it is critical to develop negative emission technologies, such as CO2 reduction electrolyzers, but these devices still suffer from various issues including low utilization of CO2 because of its cross-over from the cathode to the anode. This comment highlights the recent innovative design of membrane electrode assembly, utilizing a bipolar membrane and catholyte layer that blocks CO2 cross-over and enables high CO2 single-pass utilization.

Topics & Concepts

AnodeCathodeElectrolysisElectrodeReduction (mathematics)Membrane electrode assemblyMaterials scienceElectrolysis of waterNanotechnologyDesign elements and principlesCrossoverProcess engineeringComputer scienceEngineeringElectrical engineeringChemistryArtificial intelligenceMathematicsPhysical chemistryGeometrySoftware engineeringElectrolyteCO2 Reduction Techniques and CatalystsAdvanced battery technologies researchCarbon dioxide utilization in catalysis