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Interfacial engineered RDX/TATB energetic co-particles for enhanced safety performance and thermal stability

Yanzhou Qu, Wen Qian, Jianhu Zhang, Feiyan Gong, Zhengfeng Xie, Zhijian Yang, Fude Nie, Xu Zhao

2022Dalton Transactions18 citationsDOI

Abstract

X-ray computed tomography and a three-dimensional laser scanning confocal microscope. As a result, the impact safety performance of RT co-particles could be drastically enhanced to 17.5 J by the TATB lubricant effect, demonstrating over twice the value of that of raw RDX (6 J) and mixtures (7 J). Moreover, an interfacial reconstruction between RDX and TATB was witnessed due to the strong interfacial interaction, as examined by theoretical simulation. Inspired by this, a delayed exothermic decomposition temperature of RT co-particles (244.4 °C) has been achieved when compared with that of RDX (241.4 °C). As demonstrated, an energetic co-particle strategy may provide an effective pathway toward remarkably improved mechanical and thermal safety performance, shedding light on other energetic materials.

Topics & Concepts

TATBMaterials scienceLubricantChemical engineeringParticle (ecology)Exothermic reactionThermal stabilityEnergetic materialThermalNanotechnologyDecompositionComposite materialExplosive materialChemistryDetonationThermodynamicsOrganic chemistryEngineeringOceanographyPhysicsGeologyEnergetic Materials and CombustionThermal and Kinetic AnalysisRocket and propulsion systems research
Interfacial engineered RDX/TATB energetic co-particles for enhanced safety performance and thermal stability | Litcius