A <i>Z</i>-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex
Javier A. Cabeza, Pablo García‐Álvarez, Carlos J. Laglera‐Gándara, Enrique Pérez‐Carreño
Abstract
An unusual T-shaped palladium(0) complex having a σ-acceptor (<italic>Z</italic>-type) germylene scaffold has been prepared from a dipyrromethane-based PGeP germylene.
Topics & Concepts
Pincer movementPalladiumLigand (biochemistry)ChemistryPincer ligandCombinatorial chemistryStereochemistryOrganic chemistryBiochemistryCatalysisReceptorSynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisOrganoboron and organosilicon chemistry