One-Step Incorporation of Nitrogen and Vanadium between Ti<sub>3</sub>C<sub>2</sub><i>T</i><sub><i>x</i></sub> MXene Interlayers Enhances Lithium Ion Storage Capability
Renfei Cheng, Zuohua Wang, Cong Cui, Tao Hu, Bingbing Fan, Hailong Wang, Yan Liang, Chao Zhang, Hongwang Zhang, Xiaohui Wang
Abstract
Two-dimensional (2D) transition-metal carbide materials termed MXene have attracted huge attention in the field of electrochemical energy storage. To this end, MXenes whose capability depends on the M transition elements represent a new paradigm extending beyond the realm of oft-explored elemental 2D materials beginning with graphene. However, the as-prepared MXenes suffer from unsatisfied capability due to the loss M elements during the etching process for the preparation of MXenes. Here, taking Ti3C2Tx as an example, we demonstrate that nitrogen and vanadium incorporation by means of microwave irradiation in NH4VO3-containing ethylene glycol can significantly improve the electrochemical performance of multilayered Ti3C2Tx MXene. While maintaining the 2D structure of MXene layers, the N and V elements are incorporated between the Ti3C2Tx MXene interlayers in the forms of C–V–OH, C–V–O, V–O, and Ti–O–N species. Specifically, at a V:Ti atomic ratio of about 1:30 (N:Ti = 0.29), N and V incorporation between the Ti3C2Tx interlayers gives rise to an increase in capability by about 40%, corresponding to an impressive reversible capacity of 92 mA h g–1 at 3 C rate after 1000 cycles. These results demonstrate that N (V)-incorporated Ti3C2Tx MXenes offer fascinating potential for high-performance electrode materials and provide guidelines for designing and engineering anode materials.