Realizing Cross-linking-free Acrylic Pressure-Sensitive Adhesives with Intensive Chain Entanglement through Visible-Light-Mediated Photoiniferter-Reversible Addition–Fragmentation Chain-Transfer Polymerization
Chiwon Hwang, Sangbin Shin, Dowon Ahn, Hyun‐jong Paik, Wonjoo Lee, Youngchang Yu
Abstract
A versatile and simplified synthesis scheme for intensively entangled acrylic pressure-sensitive adhesives (PSAs) was developed in this study by leveraging visible-light-driven controlled radical polymerization (photoiniferter/reversible addition–fragmentation chain-transfer polymerization) of acrylic copolymers under a controlled manner; the approach was differentiated by a single factor; molecular weight ( M w up to 2.8 MDa) with identical compositions. By manipulating M w up to ultra-high ranges, PSAs with diversified viscoelastic properties were prepared and then assessed with a focus on realizing PSAs with a maximized degree of entanglement per chain through domination of high M w contents, to help achieve excellent cohesiveness without a reinforcing cross-linking network. Moreover, fully linear solvent-soluble poly(acrylate)s were synthesized to facilitate reprocessing and reuse, highlighting the sustainability of the devised method and, consequently, its potential to be applied for effectively reducing industrial or daily waste.