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Control of electronic polarization <i>via</i> charge ordering and electron transfer: electronic ferroelectrics and electronic pyroelectrics

Shengqun Su, Shu‐Qi Wu, Shinji Kanegawa, Kaoru Yamamoto, Osamu Sato

2023Chemical Science30 citationsDOIOpen Access PDF

Abstract

(dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone, cth = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraaza-cyclotetradecane), are introduced. Future prospects are also discussed, particularly the development of new properties in polarization switching through the manipulation of electronic polarization in electronic ferroelectrics and electronic pyroelectrics by taking advantage of the inherent properties of electrons.

Topics & Concepts

TetrathiafulvaleneFerroelectricityPolarization (electrochemistry)PyroelectricityElectronIonic bondingMaterials scienceCondensed matter physicsChemistryOptoelectronicsIonMoleculeDielectricPhysical chemistryPhysicsOrganic chemistryQuantum mechanicsOrganic and Molecular Conductors ResearchPerovskite Materials and ApplicationsMagnetism in coordination complexes
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