Ultrafast structural dynamics of in-cage isomerization of diiodomethane in solution
Hanui Kim, Jong Goo Kim, Tae Wu Kim, Sang Jin Lee, Shunsuke Nozawa, Shin‐ichi Adachi, Kihwan Yoon, Joonghan Kim, Hyotcherl Ihee
Abstract
The structural dynamics of in-cage isomerization of CH 2 I 2 and the unusual structure of the loosely-bound isomer precursor were unveiled with femtosecond X-ray liquidography (solution scattering).
Topics & Concepts
PhotoexcitationIsomerizationDiiodomethanePhotodissociationChemistryPhotochemistryCage effectCrystallographyFemtosecondExcited stateLaserPhysical chemistryAtomic physicsOrganic chemistryCatalysisPhysicsOpticsSurface energyAdvanced Chemical Physics StudiesSpectroscopy and Quantum Chemical StudiesCatalysis and Oxidation Reactions