Strong interaction between plasmon and topological surface state in Bi <sub>2</sub> Se <sub>3</sub> /Cu <sub> 2- <i>x</i> </sub> S nanowires for solar-driven photothermal applications
Yang Liu, Shengfeng Pan, Wenxi Xia, Pingli Qin, Wei Wang, Qingbo Liu, Xiang‐Bai Chen, Liang Ma, Si‐Jing Ding, Qu‐Quan Wang
Abstract
Developing high-performance photothermal materials and unraveling the underlying mechanism are essential for photothermal applications. Here, photothermal performance improved by strong interaction between plasmon and topological surface state (TSS) is demonstrated in Bi 2 Se 3 /Cu 2- x S nanowires. This hybrid, which Cu 2- x S nanosheets were grown on Bi 2 Se 3 nanowires, leverages the plasmon resonance and TSS-induced optical property, generating wide and efficient light absorption. A series of tests reveals the strong resonance coupling, TSS-induced hot electron injection, and plasmon-induced hot hole relaxation within the hybrids, endowing the Bi 2 Se 3 /Cu 2- x S with excellent photothermal performance. By integrating the hybrids into a hydrogel with a thermoelectric module, the Bi 2 Se 3 /Cu 2- x S evaporator achieves a remarkable water evaporation rate of 3.67 kilograms per square meter per hour with a solar-to-vapor efficiency of 95.2%, and a maximum output power of 1.078 watts per square meter under simulated sunlight irradiation. Moreover, a conical mirror was introduced to the device, which greatly enhances the evaporation rate and maximum output power without additional energy input.