Synthesis and reactivity of heteroleptic zinc(<scp>i</scp>) complexes toward heteroallenes
Bin Li, Kevin Huse, Christoph Wölper, Stephan Schulz
Abstract
Heteroleptic zinc( i ) complexes Cp*Zn–ZnL 1/2 were synthesized and reactions of Cp*Zn–ZnL 2 2 with t -BuNCO and organoazides RN 3 proceeded with insertion into the Zn–Zn bond and formation of novel zinc carbamate, bis-hexazene, triazenide, and azide complexes 4–7.
Topics & Concepts
Reactivity (psychology)ZincChemistryCombinatorial chemistryStereochemistryOrganic chemistryMedicineAlternative medicinePathologyOrganometallic Complex Synthesis and CatalysisCoordination Chemistry and OrganometallicsAsymmetric Synthesis and Catalysis