Recent Research Trends on Zeolitic Imidazolate Framework-8 and Zeolitic Imidazolate Framework-67-Based Hybrid Nanocomposites for Supercapacitor Application
Kisan Chhetri, Anup Adhikari, Jyotendra Kunwar, Debendra Acharya, Roshan Mangal Bhattarai, Young Sun Mok, Achyut Adhikari, Amar Prasad Yadav, Hak Yong Kim
Abstract
Recently, Zeolitic Imidazolate Frameworks (ZIFs) and their hybrid composites have incited a lot of interest in the research community and have shown promising potential in supercapacitors owing to their excellent conductivity, high surface area, tunable structure, rich redox chemistry, composition diversity, etc. Even though many ZIFs are being studied for the advancement of electrode materials used for energy storage applications, in this review, we are focused on ZIF-8 and ZIF-67 only. The electrochemical performance of pure ZIFs is poor due to low electronic conductivity and poor cycling life. To counter this, ZIFs are mixed with other materials like conducting polymers, other transitional metals composites, and activated carbons to prepare hybrid composites. Furthermore, the highly porous structure and large surface area of the ZIFs cage act as an ideal template for designing composites with excellent supercapacitor applications. This reviewis focus on the synthesis and electrochemical performance of such materials. This review is divided into two main parts: the design and synthesis of ZIF-8 and ZIF-67 derivatives for supercapacitor applications and the electrochemical performance of ZIF-8 and ZIF-67-based derivatives in three-electrode and two-electrode setups. Lastly, the challenges and obstacles encountered while employing ZIF-8 and ZIF-67-based composites in supercapacitors will be reviewed and commented on.