Visible-light-driven sustainable conversion of carbon dioxide to methanol using a metal-free covalent organic framework as a recyclable photocatalyst
Pekham Chakrabortty, Swarbhanu Ghosh, Anjan Kumar Das, Aslam Khan, Sk. Manirul Islam
Abstract
A 2D covalent organic framework (COF) was synthesized by copolymerization between 4,4′-biphenyldicarbaldehyde and 1,3,5-tris-(4-aminophenyl) triazine (TAPT). This COF exhibited excellent photocatalytic performance for the CO 2 reduction to methanol.
Topics & Concepts
MethanolPhotocatalysisCovalent bondCovalent organic frameworkTriazineCatalysisCarbon dioxideVisible spectrumMetalChemistryMaterials sciencePhotochemistryOrganic chemistryOptoelectronicsCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications