High-Performance Resistive Random Access Memories Based on Two-Dimensional HAPbI<sub>4</sub> Organic–Inorganic Hybrid Perovskite
Binglin Liu, Jun’an Lai, Daofu Wu, Liye Li, Kaijin Kang, Wei Hu, Xiaosheng Tang
Abstract
Organic–inorganic hybrid perovskites have attracted extensive attention for potential memory applications because of their excellent properties, such as high charge carrier mobility and fast ion migration. Herein, the two-dimensional HAPbI4 perovskite with an octahedral structure and high stability was prepared by a facile solution method. Moreover, the resistive random access memory (RRAM) with the Ag/PMMA/HAPbI4/ITO structure has been successfully fabricated by spin coating and vacuum thermal evaporation. The as-prepared RRAM device based on HAPbI4 demonstrated superior resistive switching performance. The on/off ratio is as high as 105, and the corresponding retention of the device exceeds 10 000 s; furthermore, the RRAM device could be kept stable after being kept in the air for 24 weeks.