Polyoxometalate-based ionic liquids: efficient reversible phase transformation-type catalysts for thiolation of alcohols to construct C–S bonds
Ji-Kun Li, Junwei Ma, Chuanping Wei, Ze-Bao Zheng, Yinfeng Han, Huiping Wang, Xueshen Wang, Changwen Hu
Abstract
(PIM = 1-propylimidazole, PS = propane sulfonate) as a reversible phase transformation-type catalyst, combining the advantages of homogeneous and heterogeneous catalysts, exhibited high activity and good recyclability with only a slight decrease in the yield after five runs. Additionally, a carbocation mechanism was proposed for the thiolation reaction of alcohols.
Topics & Concepts
PolyoxometalateCatalysisIonic liquidPhase (matter)Construct (python library)Transformation (genetics)ChemistryIonic bondingCombinatorial chemistryOrganic chemistryIonComputer scienceGeneProgramming languageBiochemistrySulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsPolyoxometalates: Synthesis and Applications