High Sensitivity Detection of Nitrite Electrochemical Sensor Modified with MOF Composite Materials
Xu-Shan Li, Xin Zou, Wenyi Chen, Qian Sun, En‐Qing Gao
Abstract
Depositing composites of Ni-HHTP and MWCNTs on a glassy carbon electrode(GCE) have developed a sensitive and facile electrochemical sensor for nitrite detection. Ni-HHTP@MWCNTs composites were synthesized in situ using 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP), nickel acetate tetrahydrate Ni(OAc) 2 ·4H 2 O and multi-walled carbon nanotubes (MWCNTs) by hydrothermal method. The composite electrode was prepared by the coating method. The synergistic combination of Ni-HHTP and MWCNTs enables the electrode to possess fast electronic conductivity and generate sensitive electrochemical signals for sodium nitrite (NaNO 2 ). The controlled variable approach determines the best test conditions for the analyte and obtains a susceptible response signal. The composite electrode has an extensive linear response range of 1–10000 μ M to NaNO 2 , with a detection limit of 0.95 μ M and sensitivity of 0.96 mA·mM −1 ·cm −2 , which shows excellent reproducibility and stability performance. There are no interferences from the most common ions. The electrochemical analysis method was used for nitrite detection in actual water samples with a recovery rate of 97.2%–103.7%, indicating this composite material’s practical application potential. The mechanism of the specific electrochemical process on the modified electrode was also explored. This work preliminarily explored new electrochemical sensors for high-precision nitrite detection and precise sensing in analysis tests.