Litcius/Paper detail

Quantifying time-dependent structural and mechanical properties of UV-aged LDPE power cables insulations

Abdallah Hedir, Ferhat Slimani, Mustapha Moudoud, Omar Lamrous, Tahar Touam, MADJID TEGUAR, ABDERRAHMANE HADDAD, Ali DURMUS

2022TURKISH JOURNAL OF CHEMISTRY10 citationsDOIOpen Access PDF

Abstract

This paper reports effects of ultraviolet (UV) light radiation on the physicochemical, electrical and mechanical properties of low-density polyethylene (LDPE) cable insulating materials. Changes in structural and morphological properties of UV-aged samples were characterized by various analytical methods such as attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM). Additionally, elongation at break, tensile strength, dielectric strength, and optical properties were also evaluated. Changes in some physical properties of LDPE after exposing to UV irradiation clearly highlighted that the polymer underwent the structural degradation. In addition, it was also found that such degradation yielded both crosslinking and chain scission as two competing processes during UV aging.

Topics & Concepts

Low-density polyethyleneFourier transform infrared spectroscopyScanning electron microscopeUltimate tensile strengthAttenuated total reflectionPolyethyleneComposite materialPolymerUltravioletElongationIrradiationDegradation (telecommunications)ChemistryInfraredMaterials scienceChemical engineeringOpticsOptoelectronicsPhysicsTelecommunicationsNuclear physicsComputer scienceEngineeringHigh voltage insulation and dielectric phenomenaMaterial Properties and ProcessingPolymer crystallization and properties