AB5-based metal hydride embedded in polyethylene and polymethylmethacrylate for hydrogen storage
Elijah Ugaddan, Davide Violi, Valentina Fiume, Jussara Barale, Carlo Luetto, Paola Rizzi, Marcello Baricco
Abstract
Loose powder in metal hydride reactors poses challenges, such as poor thermal conductivity and tube deformation. To address these issues, the metal powder can be encapsulated in a polymer-based matrix to form pellets. This encapsulation helps make the pellets oxygen-impermeable, capable of accommodating the volumetric expansion of metal hydrides, and increases system processability. This study investigates the use of polymer-based pellets containing AB5-based compounds for ambient hydrogen storage. Polymers were selected using ANSYS Granta software, and polyethylene and polymethylmethacrylate were chosen. The AB5 alloy activation in the pellet occurs efficiently after 3 min at 20 °C and 30 bar of hydrogen, facilitated by ball milling-induced reactive surfaces and increased grain boundaries. The optimized pellet, comprising 90 wt% AB5 powder in a PE matrix, exhibits stable hydrogen storage properties, with good mechanical resistance and minimal powder loss (below 3%) over 20 hydrogen sorption cycles in an in-house fabricated single-tube metal hydride reactor.