Photocatalytic and Electrochemical Borylation and Silylation Reactions
Tony Biremond, Margaux Riomet, Philippe Jubault, Thomas Poisson
Abstract
Due to their high versatility borylated and silylated compounds are inevitable synthons for organic chemists. To escape the classical hydroboration/hydrosilylation paradigm, chemists turned their attention to more modern and green methods such as photoredox chemistry and electrosynthesis. This account focuses on novel methods for the generation of boryl and silyl radicals to forge C-B and C-Si bonds from our group.
Topics & Concepts
SynthonHydroborationElectrosynthesisSilylationHydrosilylationChemistryRadicalBorylationPhotocatalysisElectrochemistryPhotochemistryOrganic synthesisOrganic chemistryCombinatorial chemistryCatalysisPhysical chemistryArylAlkylElectrodeRadical Photochemical ReactionsInnovative Microfluidic and Catalytic Techniques InnovationSulfur-Based Synthesis Techniques