Construction of planar-type defect-engineered metal–organic frameworks with both mixed-valence sites and copper-ion vacancies for photocatalysis
Yuan Guo, Chao Feng, Shixin Wang, Yuehong Xie, Changyan Guo, Ziran Liu, Naeem Akram, Yi Zhang, Yansong Zhao, Jide Wang
Abstract
This manuscript presents a facile paradigm for controllably developing planar-type defect-engineered metal–organic frameworks (DEMOFs) by systematically doping reductive defect linker vanillin (VAN) during the synthesis of HKUST-1.
Topics & Concepts
PlanarLinkerPhotocatalysisMaterials scienceCopperValence (chemistry)Metal-organic frameworkDopingMetalIonNanotechnologyChemical engineeringChemistryMetallurgyOptoelectronicsCatalysisPhysical chemistryOrganic chemistryComputer scienceEngineeringOperating systemAdsorptionComputer graphics (images)Metal-Organic Frameworks: Synthesis and ApplicationsAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in Catalysis