One-electron redox kinetics of aqueous transition metal couples Zn<sup>2+/+</sup>, Co<sup>2+/+</sup>, and Ni<sup>2+/+</sup>using pulse radiolysis
Alexandra Lisovskaya, Kotchaphan Kanjana, David M. Bartels
Abstract
The one-electron redox potentials for aqueous metal couples Co<sup>2+/+</sup>and Ni<sup>2+/+</sup>have been investigated by pulse radiolysis using their reactions with a series of reference compounds to establish the most positive upper limits of<italic>E</italic><sup>0</sup>.
Topics & Concepts
RadiolysisChemistryRedoxAqueous solutionRadiation chemistryChemical kineticsTransition metalKineticsChemical reaction kineticsElectronMetalInorganic chemistryChemical reactionRadiochemistryPhysical chemistryPhysicsNuclear physicsCatalysisOrganic chemistryQuantum mechanicsBiochemistryFree Radicals and AntioxidantsPhotochemistry and Electron Transfer StudiesElectrochemical Analysis and Applications