Highly selective ethenolysis with acyclic-aminooxycarbene ruthenium catalysts
Seunghwan Byun, Da-Ae Park, Seyong Kim, Sunghyun Kim, Ji Yeon Ryu, Junseong Lee, Sukwon Hong
Abstract
Acyclic carbene–ruthenium catalysts were developed for the ethenolysis. Remarkable catalytic efficiency (turnover numbers of 100 000) and excellent α-olefin selectivity (up to 98%) were exhibited.
Topics & Concepts
RutheniumCatalysisChemistryOrganic chemistrySynthetic Organic Chemistry MethodsCatalytic Cross-Coupling ReactionsN-Heterocyclic Carbenes in Organic and Inorganic Chemistry